Munoz-Herranz, Maria - University of East Anglia

个人简介

Paz was born in Madrid (Spain), where she studied Chemistry at the Universidad Autónoma de Madrid until June 1999, when she finished her Master in Chemistry (Organic Chemistry). In July 2001 she obtained her Diploma Thesis at the same University under the supervision of Prof. Antonio M. Echavarren (“Desarrollo de Nuevos Métodos de Formación de Enlace C-C Catalizados por Pt, Ru y Pd”. Apto), and then carried out her Ph.D. in Chemistry in the same group (October 2004. “Competing Pathways in the Cyclization of 1,6-Enynes Catalyzed by Transition Metals: Selectivity Studies”). On 22nd October 2004, she passed her viva (Summa Cum Laude) and, one week later undertook her new life as a postdoc in Bristol, in the group of Prof. Lloyd-Jones. During her time in Bristol she held the positions of Research Assistant (November 2004) working on “Synthesis of New 3,3'-Binol Derived Substituted Phosphoramidites” for the Ligand Bank (European Community's Sixth Framework Programme); Post-Doctoral Fellow from the Ministerio de Educación y Ciencia (August 2005), working in “Mechanistic and Kinetics Aspects of the Palladium-Catalyzed Cyclization of Dienes and Related Reactions”; and finally Research Associate (August 2007), working on “Development of New Protocols for Alkene Difuntionalisation” financed by the (Engineering and Physical Sciences Research Council (EPSRC), UK). In May 2009, Dr. Muñoz returned to Madrid, Spain with a prestigious Ramón y Cajal Award to work at the Insituto de Química Orgánica General (IQOG-CSIC), where she started her research into the discovery of new platinum-catalysed reactions of allenes. She joined the UEA as Lecturer in Chemistry from September 2011.

研究领域

Dr Muñoz is an organic chemist with particular interest in the discovery and development of new organic and organometallic reactions, the use of physical-organic-inorganic chemistry knowledge to study the mechanisms involved, in particular using isotopic labelling, kinetics, simulations and NMR techniques, and the application of the knowledge acquire to the synthesis and biosynthesis of Natural Products with potential biological activity. Her current research involves the discovery and development of novel transition metal-catalysed reactions of allenes, including: Platinum- and gold-catalysed addition of nucleophiles to allenes Platinum-catalysed cyclisation of bisallenes Synthesis of metal complex with allenic ligands for cancer therapy Mechanistic studies on the gold-catalysed azidation of allenes Mechanistic studies on the platinum-catalysed dihydroalkoxylation and bisindolylation of allenes

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Alonso, J. M., Quiros, M. T., Munoz, M. P.(2016)Chirality transfer in metal-‐catalysed intermolecular addition reactions involving allenesin Organic Chemistry Frontiers3.pp. 1186-1204 Full Text UEA Repository(Article) Quiros, M. T., Angulo, J., Muñoz, M. P.(2015)Kinetics of Intramolecular Chemical Exchange by Initial Growth Rates of Spin Saturation Transfer Difference Experiments (SSTD NMR)in Chemical Communications51.pp. 10222-10225 Full Text UEA Repository(Article) Munoz-Herranz, M.(2014)Silver and platinum-catalysed addition of O–H and N–H bonds to allenesin Chemical Society Reviews43.pp. 3164-3183 Full Text UEA Repository(Article) Hurtado-rodrigo, C., Hoehne, S., Munoz-Herranz, M.(2014)A new gold-catalysed azidation of allenesin Chemical Communications50.pp. 1494-1496 Full Text UEA Repository(Article) Valderas, C., de la Torre, M. C., Fernández, I., Munoz-Herranz, M., Sierra, M. A.(2013)The Gold(I)- and Silver(I)-Catalyzed Nicholas Reactionin Organometallics32.pp. 951-956 Full Text UEA Repository(Article) Munoz-Herranz, M.(2012)Transition Metal-Catalysed Intermolecular Reaction of Allenes With Oxygen Nucleophiles: A Perspectivein Organic & Biomolecular Chemistry10.pp. 3584-3594 Full Text UEA Repository(Article) Munoz-Herranz, M., de la Torre, M., Sierra, M.(2012)Platinum-Catalysed Bisindolylation of Allenes: A Complementary Alternative to Gold Catalysisin Chemistry - A European Journal18.pp. 4499-4504 Full Text UEA Repository(Article) Munoz-Herranz, M., de la Torre, M. C., Sierra, M. A.(2010)New Platinum-Catalysed Dihydroalkoxylation of Allenesin Advanced Synthesis & Catalysis352.pp. 2189-2194 Full Text UEA Repository(Article) White, I. R., Martin, D., Munoz-Herranz, M., Petersson, F. K., Henshaw, S. J., Nickless, G., Lloyd-Jones, G. C., Clemitshaw, K. C., Shallcross, D. E.(2010)Use of Reactive Tracers To Determine Ambient OH Radical Concentrations: Application within the Indoor Environmentin Environmental Science & Technology (including News & Research Notes)44.pp. 6269-6274 Full Text UEA Repository(Article) Evans, L. A., Fey, N., Lloyd-Jones, G. C., Munoz-Herranz, M., Slatford, P. A.(2009)Cryptocatalytic 1,2-Alkene Migration in a σ-Alkyl Palladium Diene Complexin Angewandte Chemie International Edition48.pp. 6262-6265 Full Text UEA Repository(Article) Munoz-Herranz, M., Lloyd-Jones, G. C.(2009)Triflic Acid Mediated Dealkylative Lactonisation via NMR-Observable Alkyloxonium Intermediatesin European Journal of Organic Chemistry2009.pp. 516-524 Full Text UEA Repository(Article) Dyke, A. M., Gill, D. M., Harvey, J. N., Hester, A. J., Lloyd-Jones, G. C., Munoz-Herranz, M., Shepperson, I. R.(2008)Decoupling Deprotonation from Metalation: Thia-Fries Rearrangementin Angewandte Chemie120.pp. 5145-5148 Full Text UEA Repository(Article) Kruck, M., Munoz-Herranz, M., Bishop, H. L., Frost, C. G., Chapman, C. J., Kociok-Köhn, G., Butts, C. P., Lloyd-Jones, G. C.(2008)BINOL-3,3′-TrifloneN,N-Dimethyl Phosphoramidites: Through-Space19F,31P Spin-Spin Coupling with a Remarkable Dependency on Temperature and Solvent Internal Pressurein Chemistry - A European Journal14.pp. 7808-7812 Full Text UEA Repository(Article) Lloyd-Jones, G. C., Munoz-Herranz, M.(2007)Isotopic labelling in the study of organic and organometallic mechanism and structure: an accountin Journal of Labelled Compounds and Radiopharmaceuticals50.pp. 1072-1087 Full Text UEA Repository(Article) Bray, K. L., Lloyd-Jones, G. C., Munoz-Herranz, M., Slatford, P. A., Tan, E. H. P., Tyler-Mahon, A. R., Worthington, P. A.(2006)Mechanism of Cycloisomerisation of 1,6-Heptadienes Catalysed by [(tBuCN)2PdCl2]: Remarkable Influence of Exogenous and Endogenous 1,6- and 1,5-Diene Ligandsin Chemistry - A European Journal12.pp. 8650-8663 Full Text UEA Repository(Article) Nieto-Oberhuber, C., López, S., Munoz-Herranz, M., Jiménez-Núñez, E., Buñuel, E., Cárdenas, D. J., Echavarren, A. M.(2006)Gold(I)-Catalyzed Intramolecular Cyclopropanation of Dienynesin Chemistry - A European Journal12.pp. 1694-1702 Full Text UEA Repository(Article) Nieto-Oberhuber, C., Munoz-Herranz, M., López, S., Jiménez-Núñez, E., Nevado, C., Herrero-Gómez, E., Raducan, M., Echavarren, A. M.(2006)Gold(I)-Catalyzed Cyclizations of 1,6-Enynes: Alkoxycyclizations andexo/endo Skeletal Rearrangementsin Chemistry - A European Journal12.pp. 1677-1693 Full Text UEA Repository(Article) Munoz-Herranz, M., Adrio, J., Carretero, J. C., Echavarren, A. M.(2005)Ligand Effects in Gold- and Platinum-Catalyzed Cyclization of Enynes: Chiral Gold Complexes for Enantioselective Alkoxycyclizationin Organometallics24.pp. 1293-1300 Full Text UEA Repository(Article) Nieto-Oberhuber, C., López, S., Munoz-Herranz, M., Cárdenas, D. J., Buñuel, E., Nevado, C., Echavarren, A. M.(2005)Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Goldin Angewandte Chemie-International Edition44.pp. 6146-6148 Full Text UEA Repository(Article) Echavarren, A. M., Méndez, M., Munoz-Herranz, M., Nevado, C., Martín-Matute, B., Nieto-Oberhuber, C., Cárdenas, D. J.(2004)Metal cyclopropyl carbenes in the reactions of alkynes with alkenes and furansin Pure and Applied Chemistry76.pp. 453-463 Full Text UEA Repository(Article)