Christmann, Mathias - Freie Universität Berlin

研究领域

Welcome to the Christmann group. We are working on the strategic and methodological challenges posed by generating complex molecular frameworks with a minimum number of synthetic steps. The topics related to this goal include method development, reaction mechanisms and total synthesis.

近期论文

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Enantiogroup-differentiating biocatalytic reductions of prochiral Cs-symmetrical dicarbonyl compounds to meso compounds M. Skoupi, C. Vaxelaire, C. Strohmann, M. Christmann, C. M. Niemeyer Chem. Eur. J. 2015, 20, accepted (-)-Englerin A: A Potent and Selective Activator of TRPC4 and TRPC5 Calcium Channels Y. Akbulut, H. J. Gaunt, K. Muraki, M. J. Ludlow, M. S. Amer, A. Bruns, N. S. Vasudev, L. Radtke, M. Willot, S. Hahn, T. Seitz, S. Ziegler, M. Christmann, D. J. Beech, H. Waldmann Angew. Chem. Int. Ed. 2015, 54, 3787-3791, (featured in: Chemical & Engineering News, 93 (9), March 2, 2015) Oxidation of Allylic and Benzylic Alcohols to Aldehydes and Carboxylic Acids D. Könning, T. Olbrisch, F. D. Sypaseuth, C. C. Tzschucke, M. Christmann Chem. Commun. 2014, 50, 5014-5016 A Formal, One-Pot β-Chlorination of Primary Alcohols and Its Utilization in the Transformation of Terpene Feedstock and the Synthesis of a C2-Symmetrical Terminal Bis-Epoxide J. Swatschek, L. Grothues, J. O. Bauer, C. Strohmann, M. Christmann J. Org. Chem. 2014, 79, 976-983 Catalytic and Stereoselective ortho-Lithiation of a Ferrocene Derivative P. Steffen, C. Unkelbach, M. Christmann, W. Hiller, C. Strohmann Angew. Chem. Int. Ed. 2013, 52, 9836-9840 Enantioselective Rauhut-Currier-Type Cyclizations via Dienamine Activation: Scope and Mechanism E. Marqués-López, R. P. Herrera, T. Marks, W. C. Jacobs, M. Christmann Synthesis 2013, 1016-1028 (Feature Article). One-Pot Oxidation/Isomerization of Z-Allylic Alcohols with Oxygen as Stoichiometric Oxidant D. Könning, W. Hiller, M. Christmann Org. Lett. 2012, 14, 5258-5261 Synthesis of β-Lactones via Catalytic Asymmetric Heterodimerization of Ketenes E. Marqués-López, M. Christmann Angew. Chem. Int. Ed. 2012, 51, 8696-8698 Enantioselective Tandem Reactions at Elevated Temperatures: One-Pot Hydroformylation/SN1 Alkylation J. Stiller, A. J. Vorholt, K. A. Ostrowski, A. Behr, M. Christmann Chem. Eur. J. 2012, 18, 9496-9499; (highlighted in Synfacts 2012, 8, 1094) Access to Skipped Polyene Macrolides by Ring Closing Metathesis: Total Synthesis of the RNA Polymerase Inhibitor Ripostatin B P. Winter, W. Hiller, M. Christmann Angew. Chem. Int. Ed. 2012, 51, 3396-3400 Transforming Terpene-Derived Aldehydes into 1,2-Epoxides via Asymmetric α-Chlorination: Subsequent Epoxide Opening with Carbon Nucleophiles P. Winter, J. Swatschek, M. Willot, L. Radtke, T. Olbrisch, A. Schäfer, M. Christmann Chem. Commun. 2011, 47, 12200-12202