高恩庆 - 华东师范大学 - 化学与分子工程学院

研究领域

硕士/博士研究生招生专业及方向：无机化学‚ 配位化学，配合物功能材料。可接收无机化学、有机化学、催化化学等方向的博士后 1. 分子磁性材料基于配位化合物尤其是配位聚合物的分子基磁体、纳米磁体的合成、结构与磁性 2. 分子多孔材料具有开放骨架的多孔配位聚合物（或金属－有机骨架材料‚ MOFs)的合成、结构、功能化及其催化等应用 3. 多功能分子材料在配位聚合物中引入两种或多种功能‚获得复合功能材料, 如多孔磁体、光磁材料等上述研究得到国家自然科学基金委、教育部新世纪优秀人才支持计划、上海市“曙光学者”计划、上海市科委等各方面的经费支持

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Zhuang, G.-M., X.-B. Li, Y.-Q. Wen, C.-Y. Tian, and E.-Q. Gao, Structures and Magnetic Properties of Manganese(II) Compounds Based on Chains with Simultaneous Carboxylate and Pseudohalide Bridges. Eur. J. Inorg. Chem. 2014, 3488. Yi, X.-C., M.-X. Huang, Y. Qi, and E.-Q. Gao, Synthesis, structure, luminescence and catalytic properties of cadmium(II) coordination polymers with 9H-carbazole-2,7-dicarboxylic acid. Dalton Trans. 2014. 43, 3691. Yang, Y., H.-F. Yao, F.-G. Xi, and E.-Q. Gao, Amino-functionalized Zr(IV) metal-organic framework as bifunctional acid-base catalyst for Knoevenagel condensation. J. Mol. Catal. A: Chem. 2014. 390, 198. Wang, Y.-Q., H.-T. Liu, Y. Qi, and E.-Q. Gao, Topological ferrimagnetic behaviours of coordination polymers containing manganese(II) chains with mixed azide and carboxylate bridges and alternating F/AF/AF'/AF'/AF interactions. Dalton Trans. 2014. 43, 11819. Wang, Y.-Q., Q. Yue, Y. Qi, K. Wang, Q. Sun, and E.-Q. Gao, Manganese(II), Iron(II), and Mixed-Metal Metal-Organic Frameworks Based on Chains with Mixed Carboxylate and Azide Bridges: Magnetic Coupling and Slow Relaxation. Inorg. Chem. 2013. 52, 4259. Wang, Y.-Q., A.-L. Cheng, P.-P. Liu, and E.-Q. Gao, Unusual composition dependence of magnetic relaxation for CoII1-xNiIIx chain-based metal-organic frameworks. Chem. Commun. 2013. 49, 6995. Wang, X., X.-B. Li, R.-H. Yan, Y.-Q. Wang, and E.-Q. Gao, Diverse manganese(ii) coordination polymers derived from achiral/chiral imidazolium-carboxylate zwitterions and azide: structure and magnetic properties. Dalton Trans. 2013. 42, 10000. Wang, K., X.-C. Yi, X. Wang, X.-B. Li, and E.-Q. Gao, Structures and magnetic properties of copper(ii) and manganese(ii) polymers derived from pseudohalides and a flexible zwitterionic dicarboxylate ligand. Dalton Trans. 2013. 42, 8748. Wang, K., Y.-Q. Wang, X.-M. Zhang, and E.-Q. Gao, Ferromagnetic interactions through double hydrogen bonding bridges in manganese(ii) coordination polymers. Dalton Trans. 2013. 42, 4533. Li, X.-B., G.-M. Zhuang, X. Wang, K. Wang, and E.-Q. Gao, Field-modified multiple slow relaxations in a metamagnet composed of cobalt(II) chains with mixed azide and tetrazolate bridges. Chem. Commun. 2013. 49, 1814. Zhang, X.-M., Y.-Q. Wang, X.-B. Li, and E.-Q. Gao, Manganese(II) coordination polymers with mixed azide and pyridylbenzoate N-oxide ligands: structures and magnetism. Dalton Trans. 2012. 41, 2026. Zhang, J.-Y., X.-B. Li, K. Wang, Y. Ma, A.-L. Cheng, and E.-Q. Gao, Synthesis, structures, and magnetic properties of four copper compounds with 2,2'-dinitrobiphenyl-4,4'-dicarboxylate. Dalton Trans. 2012. 41, 12192. Wang, Y.-Q., A.-L. Cheng, X. Wang, and E.-Q. Gao, Mixed azide and carboxylate bridged trinuclear Mn(II) and Co(II) motifs in coordination ladders: structures and magnetism. RSC Advances 2012. 2, 10352. Sun, Q., Y.-Q. Wang, A.-L. Cheng, K. Wang, and E.-Q. Gao, Entangled Metal-Organic Frameworks of m-Phenylenediacrylate Modulated by Bis(pyridyl) Ligands. Cryst. Growth Des. 2012. 12, 2234. Li, X.-B., K. Wang, Y. Ma, E.-Q. Gao, and C.-M. Liu, Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: synthesis, structure and magnetic properties. Dalton Trans. 2012. 41, 4188. Jing, X.-H., X.-C. Yi, E.-Q. Gao, and V.A. Blatov, Synthesis, structure, topology and magnetic properties of cobalt(ii) coordination polymers with 2-nitrobiphenyl-4,4'-dicarboxylic acid and bis(pyridyl) ligands. Dalton Trans. 2012. 41, 14316. Zhang, X.-M., Y.-Q. Wang, K. Wang, E.-Q. Gao, and C.-M. Liu, Metamagnetism and slow magnetic dynamics in an antiferromagnet composed of cobalt(II) chains with mixed azide-carboxylate bridges. Chem. Commun. 2011. 47, 1815. Zhang, X.-M., Y.-Q. Wang, Y. Song, and E.-Q. Gao, Synthesis, structures, and magnetism of copper(II) and manganese(II) coordination polymers with azide and pyridylbenzoates. Inorg. Chem. 2011. 50, 7284. Zhang, X.-M., K. Wang, Y.-Q. Wang, and E.-Q. Gao, Isomorphous Co(II) and Ni(II) antiferromagnets based on mixed azide- and carboxylate-bridged chains: metamagnetism and single-chain dynamics. Dalton Trans. 2011. 40, 12742. Zhang, J.-Y., Y. Ma, A.-L. Cheng, Q. Yue, Q. Sun, and E.-Q. Gao, Synthesis, structures, and magnetic properties of transition metal compounds with 2,2'-dinitrobiphenyl-4,4'-dicarboxylate and N,N'-chelating ligands. Dalton Trans. 2011. 40, 7219. Zhang, J.-Y., X.-H. Jing, Y. Ma, A.-L. Cheng, and E.-Q. Gao, Interpenetration, Self-Catenation, and New Topology in Metal-Organic Frameworks of Cobalt with Mixed Organic Linkers. Cryst. Growth Des. 2011. 11, 3681. Wang, Y.-Q., X.-M. Zhang, X.-B. Li, B.-W. Wang, and E.-Q. Gao, Magnetic systems with mixed carboxylate and azide bridges: slow relaxation in Co(II) metamagnet and spin frustration in Mn(II) compound. Inorg. Chem. 2011. 50, 6314. Wang, Y.-Q., W.-W. Sun, Z.-D. Wang, Q.-X. Jia, E.-Q. Gao, and Y. Song, Solvent-modulated slow magnetic relaxation in a two-dimensional compound composed of cobalt(II) single-chain magnets. Chem. Commun. 2011. 47, 6386. Wang, Y.-Q., Q. Sun, Q. Yue, A.-L. Cheng, Y. Song, and E.-Q. Gao, Manganese(II)-carboxylate-pseudohalide systems derived from 1,4-bis(4-carboxylatopyridinium-1-methylene)benzene: structures and magnetism. Dalton Trans. 2011. 40, 10966. Tian, H., K. Wang, Q.-X. Jia, Q. Sun, Y. Ma, and E.-Q. Gao, Selective Incorporation of Auxiliary Organic Ligands in Metal-Organic Frameworks Based on Twisted Pi-Shaped Building Blocks. Cryst. Growth Des. 2011. 11, 5167. Sun, Q., A.-L. Cheng, Y.-Q. Wang, Y. Ma, and E.-Q. Gao, Magnetic ordering in three-dimensional metal-organic frameworks based on carboxylate bridged square-grid layers. Inorg. Chem. 2011. 50, 8144. Ma, Y., N.A.G. Bandeira, V. Robert, and E.-Q. Gao, Experimental and Theoretical Studies on the Magnetic Properties of Manganese(II) Compounds with Mixed Isocyanate and Carboxylate Bridges. Chem. Eur. J. 2011. 17, 1988. Li, X.-B., J.-Y. Zhang, Y.-Q. Wang, Y. Song, and E.-Q. Gao, Tricomponent azide, tetrazolate, and carboxylate cobridging magnetic systems: ferromagnetic coupling, metamagnetism, and single-chain magnetism. Chem. Eur. J. 2011. 17, 13883. Li, X.-B., Y. Ma, X.-M. Zhang, J.-Y. Zhang, and E.-Q. Gao, Azide-Bridged Copper(II) and Manganese(II) Compounds with a Zwitterionic Tetrazolate Ligand: Structures and Magnetic Properties. Eur. J. Inorg. Chem. 2011, 4738. Jia, Q.-X., H. Tian, J.-Y. Zhang, and E.-Q. Gao, Diverse Structures and Magnetism of Cobalt(II) and Manganese(II) Compounds with Mixed Azido and Carboxylato Bridges Induced by Methylpyridinium Carboxylates. Chem. Eur. J. 2011. 17, 1040. Cheng, A.-L., Y. Ma, Q. Sun, and E.-Q. Gao, Layered and pillar-layered metal-organic frameworks based on pinwheel trinuclear zinc-carboxylate clusters. CrystEngComm 2011. 13, 2721. Zhang, X.-M., Y.-Q. Wang, and E.-Q. Gao, Chain Compounds Based on Tetranuclear Basic Copper(II) Carboxylate Clusters and Quadruple Zwitterionic Linkers: Structures and Magnetic Properties. Eur. J. Inorg. Chem. 2010, 1249.