张俊良 - 华东师范大学 - 化学与分子工程学院

个人简介

学术背景 1997年本科毕业天津大学化学系应用化学专业‚ 2002年取得有机化学博士学位‚ 师从麻生明院士‚ 2002-2003年‚在中科院上海有机所以临时工作人员身份工作一年。 2003年10月赴德国科隆大学化学系从事博士后研究‚洪堡学者奖学金获得者。 2005年赴美国芝加哥大学化学系从事博士后研究。获奖 2012：Thieme Chemistry Journal Award 2009：中国化学会青年化学家奖社会兼职上海市绿色化学与化工过程绿色化重点实验室‚第二届学术委员会委员中国化学会永久会员

研究领域

1.共轭烯炔化学成功解决了基于共轭烯炔类化合物为反应原料的多样性合成和选择性问题，首次发现了过渡金属钯和铑的路易斯酸性是实现反应的关键。被美国化学家V.Gevorgyan 在Chem. Rev. 2013,133, 3084, 评述17篇。 2.小环化学成功实现了基于三元环衍生物为反应原料的多样性合成和选择性问题。首次实现了在温和条件下，三元杂环化合物的C-C键的选择性断裂及其多样性转化。发现可以利用不同类型的路易斯酸，实现化学选择性控制。这部分工作被著名有机化学家M. Lautens 和V. Snieckus评为重要进展。 3.金催化 4.有机催化

近期论文

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Ben Ma, Zhaowei Chu, Ben Huang, Zhenli Liu, Lu Liu* and Junliang Zhang* Highly para-selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-diazoesters.Angew. Chem. Int. Ed., 2017, 56, DOI:10.1002/anie.201611809. Chao-Ze Zhu, Jian-Jun Feng* and Junliang Zhang* Rhodium(I)-Catalyzed Intermolecular Aza-[4+3] Cycloaddition of Vinyl Aziridines and Dienes: Atom-Economical Synthesis of nantiomerically Enriched Functionalized Azepines. Angew. Chem. Int. Ed., 2017, 56, DOI: 10.1002/anie.201609608. Yangyan Li,WenboLi and Junliang Zhang* Gold-Catalyzed Enantioselective Annulations. Chem. Eur. J., 2016, 22, DOI: 10.1002/chem.201602822. Bing Xu,‡ Zhan-Ming Zhang,‡ Shan Xu, Bing Liu, Yuanjing Xiao and Junliang Zhang* Copper(I)/Ming-Phos-Catalyzed Asymmetric Intermolecular [3+2] Cycloaddition of Azomethine Ylides with α-Trifluoromethyl α,β-Unsaturated Esters. ACS Catal. 2017, 7, 210−214. W. Zhou, L. Gao, M. Tao, X. Su, Q. Zhao, J. Zhang, Acta Chim. Sinica 2016, 74, 800-804. W. Zhou, Z. Yue, J. Zhang, Org. Chem. Front. 2016, 3, 1416. Zhunzhun Yu,Yongfeng Li, Jiameng Shi, Ben Ma, Lu Liu and Junliang Zhang* (C6F5)3B -Catalyzed Highly Chemoselective and Ortho-selective C-H Bond Functionalization of Phenols Oriented by Hydrogen Bonds. Angew. Chem. Int. Ed., 2016, 55, 14807-14811. Feng, Jian-Jun;* Zhang, Junliang* Synthesis of Unsaturated N-Heterocycles by Cycloadditions of Aziridines and Alkynes. ACS Catal. 2016, 6, 6651-6661. (Invited Review) http://pubs.acs.org/doi/abs/10.1021/acscatal.6b02072 Peng Chen, Zhenting Yue, Junyou Zhang, Xi Lv, Lei Wang and Junliang Zhang* Phosphine-Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita–Baylis–Hillman Carbonates. Angew. Chem. Int. Ed. 2016, 55, 13316-13320. Zhenting Yue, Wenbo Li, Lu Liu, Cuihong Wang* and Junliang Zhang* Enantioselective Synthesis of 4H-Pyrans Through Organocatalytic Asymmetric Formal [3+3] Cycloadditions of 2-(1-Alkynyl)-2-alken-1-ones with β-Keto Esters. Adv. Synth. Catal. 2016, 3015-3020 (VIP). Lin, Tao-Yan; Zhu, Chao-Ze; Zhang, Peichao; Wang, Yidong; Wu, Hai-Hong; Feng, Jian-Jun;* Zhang, Junliang* Regiodivergent Intermolecular [3+2] Cycloadditions of Vinyl Aziridines and Allenes: Stereospecific Synthesis of Chiral Pyrrolidines”, Angew. Chem. Int. Ed. 2016, 55, 10844-10848. http://onlinelibrary.wiley.com/doi/10.1002/anie.201605530/full WenboLi, Xiuzhao Yu, Zhenting Yue, and Junliang Zhang* Asymmetric Construction of 2,3-Dihydroisoxazoles via an Organocatalytic Formal [3 + 2] Cycloaddition of Enynes withN-Hydroxylamines. Org. Lett. 2016, 18, 3972–3975 Ben Ma, Ziang Wu, Ben Huang, Lu Liu* and Junliang Zhang* Gold-catalysed facile access to indene scaffold via sequential C-H functionalization and 5-endo-dig carbocyclization. Chem. Commun, 2016, 52, 9351-9354. http://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc04034a Wei Zhou, Peng Chen, Mengna Tao, Xiao Su, Qingjie Zhao* and Junliang Zhang* Enantioselective intermolecular cross Rauhut–Currier reactions of activated alkenes with acrolein. Chem. Commun, 2016, 52, 7612-7615. ZhunZhun Yu, Lu Liu* and Junliang Zhang* Triflic Acid-Catalyzed Enynes Cyclization: A New Strategy beyond Electrophilic π-Activation. Chem. Eur. J., 2016, 22, 8488-8492 Haoxiang Hu, Yidong Wang, Deyun Qian, Zhan-Ming Zhang, Lu Liu* and Junliang Zhang* Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with N-allenyl oxazolidinone. Org. Chem. Front., 2016, 3, 759-763. http://pubs.rsc.org/en/content/articlelanding/2016/qo/c6qo00087h/unauth#!divAbstract Zhan-Ming Zhang,‡ Bing Xu,‡ Shan Xu, Hai-Hong Wu and Junliang Zhang* Diastereo- and Enantioselective Copper(I)-Catalyzed Intermolecular [3+2] Cycloaddition of Azomethine Ylides with β-Trifluoromethyl β,β-Disubstituted Enones. Angew. Chem. Int. Ed. 2016, 55, 6324–6328. Jieru Yang, Xiaofan Zhou, Yu Zeng, Chaoqian Huang, Yuanjing Xiao* and Junliang Zhang* Synthesis of 2-fluoro-2-pyrrolines via tandem reaction of α-trifluoromethyl-α,β-unsaturated carbonyl compounds with N-tosylated 2-aminomalonates. Chem. Commun., 2016, 52, 4922. http://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc00831c Jian-Jun Feng,‡ Tao-Yan Lin,‡ Chao-Ze Zhu, Huamin Wang, Hai-Hong Wu and Junliang Zhang* The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes. J. Am. Chem. Soc. 2016, 138, 2178-2181. Wenbo Li and Junliang Zhang* Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands. Chem. Soc. Rev. 2016, 45, 1657-1677.