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The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks†
Chemical Science ( IF 9.969 ) Pub Date : 2023-02-15 , DOI: 10.1039/c9sc05757a Tomoya Itakura, Hiroshi Matsui, Tomofumi Tada, Susumu Kitagawa, Aude Demessence, Satoshi Horike
Chemical Science ( IF 9.969 ) Pub Date : 2023-02-15 , DOI: 10.1039/c9sc05757a Tomoya Itakura, Hiroshi Matsui, Tomofumi Tada, Susumu Kitagawa, Aude Demessence, Satoshi Horike
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We studied the relationship between proton conductivity and the terahertz-regime vibrations of two-dimensional MOFs. The results of spectroscopy studies clarified the essential role played by the collective motions in the terahertz region in 2D layers for efficient H+ conduction. Ab initio calculations suggested the collective motion to be predominantly determined by the valence electronic structure, depending on the identity of the metal ion.
更新日期：2020-01-04
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